It depends whether you want to do the switching for the battery. I never do the battery thing so I only use the outer lugs ("big" one for center ground and the outside small one for sleeve plus).
Again, the best way to commit this to memory is to use a dmm and see what happens when you plug the dc jack in and out.
EDIT: see here... green wires for ground, yellow for positive (I know, not very intuitive but it was all I had at that moment
)